FISHER SCIENTIFIC CO -- SODIUM PHOSPHATE, DIBASIC, S374 -- 6810-00-264-6594
===================== Product Identification ===================== Product ID:SODIUM PHOSPHATE, DIBASIC, S374 MSDS Date:06/17/1993 FSC:6810 NIIN:00-264-6594 === Responsible Party === Company Name:FISHER SCIENTIFIC CO Address:1 REAGENT LN City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM MONOHYDROGEN PHOSPHATE (2:1:1); (SODIUM PHOSPHATE, DIBASIC) (CERCLA) CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPDAT: AVOID GASTRIC LAVAGE OR EMETICS. ESOPHAGOSCOPY IS WAY TO EXCLUDE POSS OF CORR IN UPPER GI TRACT; IF CORR (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:IS SUSPECTED, ESOPHAGOSCOPY SHOULD ONLY BE PERFORMED W/IN 24 HRS. MAINTAIN AIRWAY & TREAT SHOCK. IF VOMIT (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: OCCURS, KEEP HEAD BELOW HIPS TO HELP PVNT ASPIR. GET MED ATTN IMMED. NOTE:FOLLOWING ANTIDOTE IS RECOM. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HOWEVER, DECISION AS TO WHETHER SEV OF POISONING REQS ADMIN OF ANTIDOTE & DOSE REQD SHOULD BE MADE BY (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: QUALIFIED MED PERS. HYPOCALCEMIA, AFTER PHOSPHATE INGEST, GIVE CALCIUM GLUCONATE, 5 ML OF SOLN SLOWLY (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: IV, TO RESTORE IONIC CALCIUM TO NORM LEVEL. ANTIDOTE SHOULD BE ADMIN ONLY BY QUALIFIED MED PERS. RTECS #:9999999ZZ Ingred Name:SPILL PROC:DREDGES/LIFTS TO EXTRACT IMMOBILIZED MASSES OF POLLUTION & PRECIPITATES. FOR LG SPILLS, SWEEP UP WITH (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:MIN OF DUSTING & PLACE INTO SUITABLE CLEAN, DRY CNTNRS FOR RECLAMATION/LATER DISP. RESIDUE SHOULD BE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CLEANED UP USING HIGH-EFFICIENCY PARTICULATE FILTER. RQ:5000 LBS. SARA REQS RELS EQUAL TO/GREATER THAN RQ (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:BE IMMED REPORTED TO LOC EMER PLANNING COMMITTEE & STATE EMER RESPONSE COMM. IF REPORTABLE UNDER CERCLA, (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: THE NRC MUST BE NOTIFIED IMMED AT 804-424-8802. RTECS #:9999999ZZ Ingred Name:RESP PROT: NOT EXCEED WORKING LIMS OF RESP & MUST BE NIOSH/MSHA APPRVD. ANY CHEM CARTRIDGE RESP W/ORG VAP (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CARTRIDGE(S) W/FULL FACEPIECE IN COMBINATION W/DUST & MIST FILTER. ANY POWERED AIR-PURIFYING RESP WITH A (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: TIGHT-FITTING FACEPIECE & ORG VAP CARTRIDGE(S) IN COMBINATION W/HIGH-EFFICIENCY PARTICULATE FILTER. ANY (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: TYPE 'C' SUPPLIED-AIR RESP W/FULL FACEPIECE OPERATED IN PRESS-DEMAND OR OTHER POS PRESS MODE. ANY SCBA (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: W/FULL FACEPIECE OPERATED IN PRESS-DEMAND OR OTHER POSITIVE PRESSURE MODE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 17 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE MILD IRRIT OF MUC MEMB W/SORE THROAT, COUGH, CHOKING & DFCLTY BRTHG. SKIN: CNTCT MAY PRDCE MILD IRRIT & REDNESS. EYES: MAY CAUSE MILD IRRIT W/REDNESS & PAIN. INGEST: MAY RSLT I N PAIN & BURNING IN MOUTH, ABDOM PAIN, NAUS, VOMIT, DIARR & CRAMPS. PHOSPHATES MAY CAUSE SHOCKLIKE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: STATE, FALL OF BLOOD PRESS, SLOW PULSE, CYANOSIS, & SOMETIMES TETANY AS RSLT OF REDUCTION IN IONIC CALCIUM. CHRONIC: SKIN: RPTD/PRLNG EXPOS MAY CAUSE DERM. INGEST: ANIMALS FED SODIUM PHOSPHA TE DIBASIC & POTASSIUM HYDROGEN PHOSPHATE HAD GREATER DEGREE OF BONE POROSITY THAN CONTROLS IN BOTH SHORT & (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF BRTHG STOPPED, PERFORM ARTF RESP. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH AFFE CTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LG AMTS OF WATER/NORM SALINE, OCCAS LIFTING UPPER (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINGUISH USING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING FUMES OR DUSTS; KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP IN HOLDING AREA SUCH AS PIT, POND/LAGOON TO CNTN SPILLED MATL. USE PROT COVER SUCH AS PLASTIC SHEET TO PVNT DISSOLVING IN FIRE FIGHTING WATER/RAIN. NEUT W/AGRICULTURAL LIME, SLAKED LIME, CRUSHED LIMESTONE OR SODIUM PHOSPHATE. USE MECH(ING 8) Neutralizing Agent:NEUT W/AGRICULTURAL LIME, SLAKED LIME, CRUSHED LIMESTONE OR SODIUM PHOSPHATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CLOSED. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:AVOID DISPERSION OF DUST IN AIR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOWING RESPS ARE RECOM BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. RANKED IN ORDER FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, SPECIFIC OPERATION, MUST (ING 13) Ventilation:LOCAL EXHAUST VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYE WASH FOUNTAIN & DELUGE SHOWER . WEAR APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT CNTCT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 9.1 @ 1% SOLN. EFTS OF OVEREXP: LONG TERM STUDIES. ALSO EVID OF HYPERPARATHYROIDISM & SOFT TISS CALCIFICATION. FIRST AID PROC: & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET M ED ATTN IMMED. INGEST: DILUTE ALKALI BYGIVING WATER OR MILK IMMED & ALLOWING VOMIT TO OCCUR. (ING 2) ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.066 (2H*2O) pH:SUPDAT Solubility in Water:12.5% Appearance and Odor:ODORLESS, HYGROSCOPIC, COLORLESS TRANSLUCENT CRYSTALS OR WHITE W/A SALTY TASTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PHOSPHATE, DIBASIC: (STRONG); POSS VIOLENT REACTION. ALUMINUM: MAY CORRODE. METALS: MAY CORRODE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC AND HAZARDOUS SODIUM OXIDE AND OXIDES OF PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF SUBSTANCES. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.