MALLINCKRODT BAKER, INC. -- TIN METAL -- 6810-00-241-1186
===================== Product Identification ===================== Product ID:TIN METAL MSDS Date:11/17/1999 FSC:6810 NIIN:00-241-1186 Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;202-483-7616 Resp. Party Other MSDS Num.:T3445 Preparer's Name:STRATEGIC SERVICES DIV Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 100% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALTION: NO ADVERSE EFFECTS EXPECTED BUT DUST MAY CAUSE MECHANICAL IRRITATION. INGESTION: LARGE DOSES MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA. SKIN: NO ADVERSE EFFECTS EXPECTED. MAY CAUSE MILD IRRI TATION AND REDNESS. EYE: NO ADVERSE EFFECTS EXPECTED BUT DUST MAY CAUSE MECHANICAL IRRITATION. CHRONIC: PROLONGED INHALTION OF DUST OR FUME MAY RESULT IN A BENIGN PNEUMOCONIOSIS, PRODUCING DISTINCTIVE CHANGES IN THE LUNGS WITH NO APPARENT DISABILITY OR COMPLICATIONS Effects of Overexposure:INHALTION: NO ADVERSE EFFECTS EXPECTED BUT DUST MAY CAUSE MECHANICAL IRRITATION. INGESTION: LARGE DOSES MAY CAUSE NAUSEA, VOMITING, AND DIARRHEA. SKIN: NO ADVERSE EFFECTS EXPECTED. MAY CAUSE MILD IRRI TATION AND REDNESS. EYE: NO ADVERSE EFFECTS EXPECTED BUT DUST MAY CAUSE MECHANICAL IRRITATION. CHRONIC: PROLONGED INHALTION OF DUST OR FUME MAY RESULT IN A BENIGN PNEUMOCONIOSIS, PRODUCING DISTINCTIVE CHANGES IN THE LUNGS WITH NO APPARENT DISABILITY OR COMPLICATIONS Medical Cond Aggravated by Exposure:NO ADVERSE HEALTH EFFECTS EXPECTED. ======================= First Aid Measures ======================= First Aid:INHALATION/SKIN: NOT EXPECTED TO REQUIRE FIRST AID MEASURES; IF INHALED REMOVE TO FRESH AIR. GET MEDICAL ATTENTIION FOR ANY BREATHING DIFFICULTY. WASH EXPOSED SKIN WITH SOAP AND WATER. GET MEDICAL AD VICE IF IRRITATION DEVELOPS. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. EYE: WASH WITH RUNNING WATER. GET MEDICAL AD VICE IF IRRITATION DEVELOPS. ===================== Fire Fighting Measures ===================== Autoignition Temp:=430.C, 806.F Autoignition Temp Text:DUST Extinguishing Media:USE DRY SAND, GRAPHITE, DOLMITE, SODIUM CHLORIDE. NEVER USE WATER, HALOGENATED AGENTS, OR CLASS A, B, OR C EXTINGUISHERS. Fire Fighting Procedures:USE PROTECTIVE CLOTHING AND BREATHING EQUIPMENT APPROPRIATE FOR THE SURROUNDING FIRE. Unusual Fire/Explosion Hazard:FINE DUST DISPERSED IN AIR IN SUFFICIENT CONCENTRATIONS, AND IN PRESENCE OF IGNITION SOURCE IS POTENTIAL DUST EXPLOSION HAZARD. MINIMUM EXPLOSIBLE CONCENTRATION: 0.19G/L PARTICLE SIZE AND AIR CONCENTR ATION DETERMINE REACTIVITY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. CLEAN UP SPILL IN A MANNER THAT DOES NOT DISPERSE DUST INTO THE AIR. USE NON-SPARKING T OOLS AND EQUIPMENT. REDUCE AIRBORNE DUST AND PREVENT SCATTERING BY MOISTENING WITH WATER. PICK UP SPILL FOR RECOVERY OR DISPOSAL AND PLACE IN A CLOSED CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM AWAY SOURCE OF HEAT OR IGNITION. .. CONTAINERS OF THIS MATERIAL MAY BE HAZAR DOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLID), OBSERVE ALL LABEL WARNINGS Other Precautions:AVOID BREATHING DUST. USE WITH ADEQUATE VENTIALTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE LIMIT(EL) IS EXCEEDED A1/2 FACE DUST/MIST RESPIRATOR MAY BE WORN FOR UP TO TEN TIMES THE EL OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY APPROPRIATE REGULATORY AGENCY OR SUPPLIER,WHICHEVE R IS LOWEST.A FULL-FACE PIECE DUST/MIST RESPIRATOR MAY BE WORN UP TO 50 TIMES THE ELI. IF EXPOSURE LEVELS UNKNOWN USE A FULL FACE + PRESSURE AIR SUPPLIED RESP Ventilation:LOCALAND ORGENERAL EXHAUST TO KEEP EXPOSURE BELOW AIRBORNE EXPOSURE LIMITS. LOCAL EXHAUST IS GENERALLY PREFERED. Protective Gloves:WEAR PROTECTIVE GLOVES Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:MAINTAIN EYE-WASH FOUNTAIN AND QUICK-DRENCH FACILITIES. CLEAN BODY-COVERING CLOTHING. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SYNONYMS: TIN; TIN FLAKE; TIN GRANULAR; STANNUM. JT BAKER CODES: 4144, 4150. MALLINCKRODT CODES: 8556. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:=2507.C, 4544.6F Melt/Freeze Pt:=231.9C, 449.4F Vapor Pres:1 @1609C Spec Gravity:7.31 pH:NO INFO Evaporation Rate & Reference:UNKNOWN(BUAC=1) Solubility in Water:INSOLUBLE Appearance and Odor:UNIFORM, SILVERY GRANULES OR MOSSY FLAKES WITH NO ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HALOGENS AND HALOGEN TRIFLUORIDES, CUPRIC NITRATE, SODIUM, POTASSIUM PEROXIDE, SULFUR, AND SOME ACIDS. Stability Condition to Avoid:WILL OXIDIZE IN PRESENCE OF MOISTURE.METAL HAS PROTECTIVE FILM OF STANNIC OXIDE WHICH THICKNESS AS TEMPERATURE IS RAISED.CONDITIONS TO AVOID: HEAT,FLAMES,IGNITION SOURCES&INCOMPATIB Hazardous Decomposition Products:PER MFG'S MSDS NO HAZARDOUS DECOMPOSITION PRODUCTS. =================== Toxicological Information =================== Toxicological Information:NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE INVESTIGATED AS A TUMORIGEN. TIN (7440-31-5) NTP CARCINOGEN: NOT KNOWN & NOT ANTICIPATED. IARC CATEGORY: NONE ===================== Ecological Information ===================== Ecological:ENVORONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICOLOGY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT AN APPROVED WASTE DISPOSAL FACILITY. STATE AND LOCAL DISPOSAL REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH FEDERAL, ST ATE AND LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED ===================== Regulatory Information ===================== SARA Title III Information:TIN (7440-31-5) SARA 302 RQ=NO, TPQ= NO. SARA 313 LIST= NO. SARA 311/312, ACUTE=YES. CHRONIC= YES. FIRE= NO. PRESSURE= NO Federal Regulatory Information:TIN (7440-31-5) CERCLA= NO. RCRA 261.33= NO, TSCA 8(D)= NO State Regulatory Information:TIN (7440-31-5) SARA 302 RQ= NO, TPQ= NO, CERCLA= NO. TSCA 8 (D)= NO. RCRA 261.33= NO ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.