FISHER SCIENTIFIC CO CHEMICAL DIV. -- SODIUM BISMUTHATE -- 6810-00-234-8368
===================== Product Identification ===================== Product ID:SODIUM BISMUTHATE MSDS Date:05/18/1988 FSC:6810 NIIN:00-234-8368 === Responsible Party === Company Name:FISHER SCIENTIFIC CO CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 OR 201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BISMUTHATE. CAS:12232-99-4 RTECS #:VZ1750000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED BY M. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50:720 MG/KG Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-MAY BE MILDLY IRRITATING TO EYES, SKIN AND PULMONARY TRACT. INGESTION OF SOME BISMUTH SALTS MAY CAUSE FOUL BREATH, STOMATITIS AND GINGIVITIS. CHRONIC-BLACK LINE ON GEMS, ENCEPHALOPATHY. Effects of Overexposure:INGESTION:ABDOMINAL PAIN, NAUSEA & VOMITING. LG.DOSES MAY CAUSE SERIOUS DIARRHEA & DEATH. SKIN/EYE:MILD IRRITATION. Medical Cond Aggravated by Exposure:IMPAIRED KIDNEY FUNCTION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR, GET MED ATTENTION FOR BREATHING DIFFICULTY. INGESTION: GIVE 2 TO 4 GLASSES OF WATER AND INDUCE VOMITNIG BY TOUCHING FINGER DOWN THROAT, CALL A PHYSICIAN IMMEDIATELY. E YE:FLUSH WITH WATER UNTIL MATERIAL IS WASHED OUT OF EYES, CONSULT PHYSICIAN. SKIN:WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH- APPROVED SCBA W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE FIRE HAZ. NOT CONCERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF SPILL, CLEAN UP PERSONNEL MAY REQUIRE RESP PROT FROM DUST. VACUUM UP OR SWEEP & CONTAINERIZE FOR RECLAMATION OR DISPOSAL. AVOID DUST DISPERSAL. DO NOT FLUSH WITH WATER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORE IN A COOL DRY VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF TLV IS EXCEEDED OR WHEN SPRAYING OR USING IN CONFINED SPACES. Ventilation:LOCAL OR GENERAL EXHAUST. Protective Gloves:WEAR PROTECTIVE GLOVES Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN & QUICK-DRENCH FACILITIES IN WORK AREA. Work Hygienic Practices:OBSERVE GOOD WORK HYGIENIC PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW OR BROWNISH YELLOW POWDER SOMEWHAT HYGROSCOPIC, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Stability Condition to Avoid:SLOWLY DECOMPOSES ON KEEPING; DECOMPOSITION ACCELERATED BY MOISTURE. Hazardous Decomposition Products:EMITS FUMES OF BISMUTH & SODIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.