SHERWIN-WILLIAMS CO -- 1503 ANTIQUE WHITE, INDUSTRIAL MAINTENANCE (SUPDAT) -- 8010-00N078233
===================== Product Identification ===================== Product ID:1503 ANTIQUE WHITE, INDUSTRIAL MAINTENANCE (SUPDAT) MSDS Date:09/01/1996 FSC:8010 NIIN:00N078233 Status Code:A === Responsible Party === Company Name:SHERWIN-WILLIAMS CO Address:31500 SOLON RD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-777-2966 Emergency Phone Num:215-566-2917 CAGE:DO642 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV. Address:6830 COCHRAN RD. Box:6709 City:SOLON State:OH ZIP:44139-3908 Phone:216-292-7400 CAGE:DO642 Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP: 760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:BUTANE. VP: 760. CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 6% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:ETHYLBENZENE (SARA 313). VP: 7.1. CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 7% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1-BUTANOL (SARA 313) (CERCLA). VP: 5.5. CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:50 PPM, S, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP: 180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 38% OSHA PEL:1000 PPM ACGIH TLV:750 PPM; 1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (SARA 313) (CERCLA). VP: 70. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 4% OSHA PEL:200 PPM ACGIH TLV:200 PPM; 300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYLISOBUTYL KETONE (SARA 313) (CERCLA). VP: 18. CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 3% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-METHOXY-2-PROPANOL ACETATE. VP: 1.8. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 7% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUND BY WEIGHT PER BAAQMD RULE 49: 43.9%; VOC TOTAL: 2.95 LBS/GAL. RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SYS DMG. WARNING:THESE PRODS CNTN CHEM/S KNOWN TO STATE OF CA TO CAUSE CANCER & BIRTH DEFECTS/OTHER REPRO HARM. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W FED, STATE & LOCAL REGS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PRECS: VENTD - DO NOT SMOKE - EXTING ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF STOVES, ELEC TOOLS(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:& APPLIANCES & ANY OTHER IGNIT SOURCES. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. CONTENTS(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMPS >120F. HEAT FROM SUNLIGHT, RADIA, STOVES, HOT (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: OF DRIED FILM. IF NO SPECIFIC DUSTS LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT: FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPS OR SPR AY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: PRLNGD OVEREXP TO SOLV INGREDS LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYS. METHYL ETHYL KETONE MAY INCR NERVOUS SYS EFTS OF OTHER SOLVS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT (ING 12) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH EYES W/LARGE AMT S OF WATER FOR AT LEAST 15 MIN. GET MEDATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:1.0% Upper Limits:13.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT) Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE - KEEP AREA (ING 15) Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES LISTED "AS DUST" IN INGRED SECTION WHICH MAY CONTAIN MATLS CLASS IFIED AS NUISANCE PARTICULATES (ING 19) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR NIOSH APPRVD, PROPERLY FITTED ORG VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED (ING 22) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.84, 107, 108. Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:USE ONLY W/ADEQUATE VENT. AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: & TOUCH UP SPRAY COLORS. FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQS SPEC PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE A HEALTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.804 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING METHYL ETHYL KETONE OR COPPE R MAY REQ TESTING FOR EXTRACTABILITY. DO (ING 14) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.