ALDON CORP. -- CALCIUM METAL -- -
===================== Product Identification ===================== Product ID:CALCIUM METAL MSDS Date:01/31/1996 FSC:NIIN:Submitter:D DG === Responsible Party === Company Name:ALDON CORP. Address:1533 W HENRIETTA RD City:AVON State:NY ZIP:14414 Country:US Info Phone Num:716-226-6177 Emergency Phone Num:716-226-6177 Resp. Party Other MSDS Num.:CC 30 Preparer's Name:MICHAEL RASZEJA Chemtrec Ind/Phone:(800)424-9300 CAGE:6V042 === Contractor Identification === Company Name:AL-DON CHEMICALS INC Address:1533 W HENRIETTA RD Box:City:AVON State:NY ZIP:14414-9508 Country:US Phone:716-226-6177 CAGE:6V042 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-A-0024-0020 CAGE:63759 Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-A-0024-0090 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM METAL CAS:7440-70-2 RTECS #:EV8040000 = Wt:98. Ingred Name:MAGNESIUM METAL CAS:7439-95-4 RTECS #:OM2100000 = Wt:.6 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYES: SEVERLY IRRITATING. MAY CAUSE INJURY TO EYE TISSUE. SKIN: CAUSES IRRITATION AND POSSIBLE CORROSION DAMAGE. INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION, COUGH AND CHEMICAL PNEUMONITIS. ING ESTION: MAY CAUSE IRRITATION OR BURNS TO MOUTH, THROAT AND STOMACH.MAY CAUSE VOMITING. SOLID MATERIAL WILL CAUSE SKIN AND EYE BURNS SINCE IT REACTS WITH MOISTURE TO FORM CAUSTIC. SIMILARLY, THE FUMES FROM BURNING CALCIUM ARE HIGHLY IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES. Effects of Overexposure:SOLID MATERIAL WILL CAUSE SKIN AND EYE BURNS SINCE IT REACTS WITH MOISTURE TO FORM CAUSTIC. SIMILARLY, THE FUMES FROM BURNING CALCIUM ARE HIGHLY IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES. ======================= First Aid Measures ======================= First Aid:SKIN: WIPE EXCESS METAL FROM SKIN. WASH WITH SOAP AND WATER. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET PROMPT MEDICAL ATTENTION. INGE STION: IF CONSCIOUS, GIVE WATER TO DRINK. DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION AS DUST OR FUME: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. SEEK IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE DRY GRAPHITE, SODA ASH, POWDERED SODIUM CHLORIDE, AND G-I POWDER. Fire Fighting Procedures:DO NOT USE WATER OR HALOGENATED HYDROCARBONS SUCH AS CARBON TETRACHLORIDE. CARBON DIOXIDE AND DRY CHEMICALS ARE INEFFECTIVE. WEAR A SELF-CONTAINED BREATHING APPARATUS; WEAR GOGGLES. USE:SPECIAL MIXTUR ES OF DRY CHEMICAL OR LIME IS ONLY EXTINGUISHING AGENT TO BE USED. Unusual Fire/Explosion Hazard:CALCIUM REACTS WITH WATER TO FORM THE HYDROXIDE & HYDROGEN. MIXED WITH AIR, THE LIBERATED HYDROGEN MAY PRESENT AN EXPLOSION HAZARD. EXPLOSION OR VIOLENT REACTION MAY TAKE PLACE IF CARE IS NOT EXERCISE D IN SELECTING EXTINGUISHANTS APPLIED TO A CALCIUM FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT AND CLOTHING. COLLECT SPILLED MATERIAL FOR RECLAMATION OR DISPOSAL IN SEALED CONTAINERS. AVOID CONTACT WITH WATER. AVOID INHALATION OF DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. NO SMOKING OR OPEN FLAMES WHEN OPENING CONTAINER. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:STORE UNDER KEROSENE OR OTHER NEUTRAL OIL. NEVER STORE UNDER HALOGENATED HYDROCARBONS. REMOVE AND WASH CONTAMINATED CLOTHING. FOR LABORATORY USE ONLY. KEEP OUT OF REACH OF CHILDREN. SO NOT WEAR CONTAC T LENSES WHEN WORKING WITH CHEMICALS. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NONE NEEDED. A NIOSH/MSHA APPROVED DUST FILTER MASK IF NEEDED. Ventilation:LOCAL/MECHANICAL:RECOMMENDED Protective Gloves:RUBBER. Eye Protection:CHEMICAL SAFETY GLASSES. Other Protective Equipment:SAFETY GOGGLES, FACE SHIELD, SMOCK, APRON, EYE WASH STATION AND A FIRE EXTINGUISHER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WARD'S P/N: 37W0998. UNUSUAL FIRE AND EXPLOSION HAZARD: FINELY DIVIDED CALCIUM IS CONSIDERED PYROPHORIC AND WILL CAUSE AN EXPLOSION WHEN AN IGNITION SOURCE IS APPLIED. MODERATE EXPLOSION HAZARD IN INT IMATE CONTACT WITH VERY POWERFUL OXIDIZING AGENTS. ================== Physical/Chemical Properties ================== HCC:R2 Boiling Pt:=1490.C, 2714.F Melt/Freeze Pt:=839.C, ######F Vapor Pres:2.0MM Vapor Density:1.4 Spec Gravity:1.54 Evaporation Rate & Reference:NON-VOLATILE Solubility in Water:VIOLENT REACTION Appearance and Odor:SILVER-WHITE SURFACE(CUT) TO GRAY-WHITE(AIR);NO ODOR.GRANULAR,TURNING/NODULES. Percent Volatiles by Volume:NON-VOLATILE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MOISTURE FROM ANY SOURCE, ALKALI-METAL HYDROXIDES AND CARBONATES, ACIDS AND ORGANIC MATERIALS. Stability Condition to Avoid:UNSTABLE WHEN EXPOSED TO MOIST ATMOSPHERE-HEAT. ACIDS. Hazardous Decomposition Products:CALCIUM AND WATER REACT TO PRODUCE HYDROGEN. BURNING CALCIUM IS SELF-SUSTAINING AND STRONGLY REDUCING TO ADJACENT MEDIA. Conditions to Avoid Polymerization:WILL NOT OCCUR =================== Toxicological Information =================== Toxicological Information:NONE ESTABLISHED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. RECYCLE OR DISPOSE OF IN AN APPROVED INCINER ATOR OR CONTRACT WITH A LICENSED CHEMICAL WASTE DISPOSAL SERVICE. =================== MSDS Transport Information =================== Transport Information:PSN: CALCIUM, 4.3, UN 1401, PG II. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.