SPECTRUM CHEMICAL MFG CORP -- XYLENE -- 6810-00N051209
===================== Product Identification ===================== Product ID:XYLENE MSDS Date:11/08/1991 FSC:6810 NIIN:00N051209 === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG CORP Address:14422 SOUTH SAN PEDRO ST City:GARDENA State:CA ZIP:90248 Country:US Info Phone Num:213-516-8000 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:63415 === Contractor Identification === Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE (SARA 313) (CERCLA) LD50 (ORAL RAT): 4300 MG/KG CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 100% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUP DAT: 2 MILE IN ALL DIRECTIONS IF TANK, RAIL CAR/TANK TRUCK IS INVOLVED IN FIRE. USE WATER IN FLOODING AMTS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: AS FOG OR SOLID STREAMS, MAY SPREAD FIRE. CONTACT NEHC FOR MORE SPECIFIC INFORMATION . RTECS #:9999999ZZ Ingred Name:EXPLO HAZ: IGNIT. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO SOURCE OF IGNIT & FLASH BACK. VAP-AIR MIXS EXPLO. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: EYE: 200 PPM HAS CAUSED CONJ IRRIT; AT HIGHER CONCS, IRRIT MAY BE SEV. VAP EXPOS HAS CAUSED (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: TEARING & PHOTOPHOBIA. ACCIDENTAL SPLASH CAUSED TRANSIENT SUPERFICIAL DMG W/RAPID RECOVERY. INGEST: MAY (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: CAUSE BURNING SENSATION IN MOUTH & STOM, SEV GI DISTRESS W/NAUS & VOMIT, & TOX EFTS INCL SIGNS OF CNS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: DEPRESS & OTHER SYMPS AS IN ACUTE INHAL. 15-30 ML (ABOUT 1/2-1 OZ) EXPECTED HUMAN LETHAL DOSE. W/ASPIR OF (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: EVEN FEW ML INTO LUNGS, SEV COUGH, DISTRESS, CHEM PNEUMIT, RAPIDLY DEVEL PULM EDEMA, & HEMORR MAY OCCUR. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: CHRONIC: INHAL: RPTD INHAL OF VAPS > 200 PPM MAY CAUSE NAUS, VOMIT, ABDOM PAIN, ANOREXIA, HDCH, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: IRRITABILITY, BRTHG DFCLTY & FLATULENCE. EFTS ON NERV SYS MAY RSLT IN EXCITATION, PARESTHESIAS, TREMORS,(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: IMPAIRED MEMORY, INSOMNIA & TINNITUS. EFTS ON LIVER, KIDNEY, CARDIOVASCULAR SYS & BONE MARROW HAVE BEEN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: REPORTED. RPTD EXPOS OF LAB ANIMALS HAS RSLTD IN MATERNAL EFTS & EFTS ON FERTILITY, ON EMBRYO/FETUS, & (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SPECIFIC DEVEL ABNORM. SKIN: MAY CAUSE DEFAT W/DRYING, ERYTHEMA, CRACKING, THICKENING & BLISTERING. (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: EYE: MAY CAUSE BURNING SENSATION, CONJ & BLURRED VISION; REVERSIBLE VACUOLAR, EPITHELIAL KERATOPATHY (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: HAS BEEN REPORTED IN SOME WORKERS. INGEST: RPTD INGEST OF MIXED, META-, OR PARA-ISOMERS BY PREGNANT MICE(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: RSLTD IN EFTS ON FERTILITY, ON EMBRYO/FETUS, OR SPECIFIC DEVEL ABNORM. CONT NEHC FOR MORE SPECIFIC INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INGEST: EXTREME CARE MUST BE USED TO PVNT ASPIR. GASTRIC LAVAGE W/CUFFED ENDOTRACHEAL TUBE IN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: PLACE TO PVNT FURTHER ASPIR SHOULD BE DONE W/IN 15 MIN. IN ABSENCE OF DEPRESS/CONVLS/IMPAIRED GAG REFLEX(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: EMESIS CAN ALSO BE INDUCED USING SYRUP OF IPECAC W/OUT INCR HAZ OF ASPIR. GASTRIC LAVAGE SHOULD BE (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: PERFORMED BY QUALIFIED MED PERS. GET MED ATTN IMMED. NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: HAZ AREA. ISOLATE HAZ AREA & RESTRICT ENTRY. REPORTABLE QTY (RQ): 1000 POUNDS. RTECS #:9999999ZZ Ingred Name:OTHER PREC: OUTSIDE/DETACHED STOR IS PREF. INSIDE STOR SHOULD BE IN STD FLAM LIQS STOR ROOM/CABINET. SEPARATE (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: FROM OXIDIZING MATLS. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: 1000 PPM IDLH. IRRIT OF UPPER RESP TRACT MAY OCCUR AT 200 PPM. HIGHER CONCS MAY CAUSE MORE SEV IRRIT & INITIAL CNS EXCITATION FOLLOWED BY DEPRESS. SIGNS & SYMPS INCL RESP DFCLTY, EUPHORI A, HDCH, NAUS, VOMIT, DIZZ, DROW, STAG.HIGH CONCS MAY CAUSE DEATH FROM SUDDEN VENTRICULAR (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: FIBRILLATION, BUT MORE FREQUENTLY DEATH OCCURS FROM RESP ARREST. SKIN: LIQ IS DEFAT AGENT & MAY CAUSE BURNING SENSATION, DRYING, VASOLIDATION, ERYTHEMA & POSS BLISTERING. READILY ABSORBED TH RU INTACT/BROKEN SKIN AT RATE OF APPROX4-10 MG/M2/HR, BUT SYSTEMIC EFTS HAVE NOT BEEN REPORTED. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF RESP. KEEP WARM & AT REST. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AREA W/SOAP & WATER UNTIL NO EVIDENCE OF CHEM REMAINS (15-20 MIN). GET MED ATTN IMMED. EYE: WASH IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (15-20 MIN). GET MED ATTN IMMED. (ING 18) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>81F,>27C Lower Limits:1.0% Upper Limits:7.0% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CONTRS FROM FIRE IF W/OUT RISK. APPLY COOLING WATER TO SIDES OF CONTRS EXPOSED TO FLAMES UNTIL (SUP DAT) Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOSED TO HEAT/FLAME. DUE TO LOW ELECTROCONDUCTIVITY, FLOW/AGITATION MAY GENERATE ELECTROSTATIC CHARGES RSLTG IN SPKS W/POSS (ING 4) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. SML SPILL: TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CONTRS FOR LATER DISP. LGE SPILL: DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMKNG, FLAMES/FLARES IN (ING 22) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:VAPS MAY BE EXPLO. AVOID OVERHEATING CONTRS; THEY MAY VIOLENTLY RUPTURE IN HEAT OF FIRE. AVOID CONTAM OF WATER SOURCES. STORE I/A/W 29 CFR 1910.106. Other Precautions:SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPKS, SHOULD BE STORED IN CONTRS WHICH MEET BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, REC PRACT ON STATIC EL EC. PROT AGAINST PHYSICAL DMG. (ING 23) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP MUST BE NIOSH APPRVD. 1000 PPM: ANY CHEM CARTRIDGE RESP W/ORG VAP CARTRIDGE(S); ANY POWERED AIR-PURIFYING RESP W/ORG VAP CARTRIDGE(S); ANY SUPP-AIR RESP; ANY SCBA. CONT NEHC FOR COMPLETE LIST OF APPRVD RESPS . Ventilation:PROVIDE LOCAL EXHAUST/GEN DILUTION VENT TO MEET PUBLISHED EXPOSURE LIMITS. VENT EQUIPMENT MUST BE EXPLOSION-PROOF. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ; IF THIS IMPOSS, WITHDRAW FROM AREA & LET FIRE BURN. WITHDR AW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>280F,>138C Melt/Freeze Pt:M.P/F.P Text:>-54F,>-48C Vapor Pres:7-9 @ 20C Vapor Density:3.7 Spec Gravity:0.8611-0.8802 Evaporation Rate & Reference:0.6 (BUTYL ACETATE=1) Solubility in Water:0.00003% Appearance and Odor:LIGHT COLORED OR COLORLESS MOBILE LIQUID WITH AROMATIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NITRIC ACID, STRONG OXIDIZERS, LASTICS, RUBBER, COATINGS, SULFURIC ACID. Stability Condition to Avoid:AVOID CONTACT WITH HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DUSPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WAST NUMBER U239. OBSERBE ALL FEDERAL, STATE & LOCAL REGULATIONS. FOR ASSIST, CONT DISTRICT DIRE CTOR OF ENVIRONMENTAL PROTECTION AGENCY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.