E I DUPONT DE NEMOURS & CO INC -- CHROMABASE CLEAR, 7500S -- 8010-00N015242
===================== Product Identification ===================== Product ID:CHROMABASE CLEAR, 7500S MSDS Date:04/01/1989 FSC:8010 NIIN:00N015242 === Responsible Party === Company Name:E I DUPONT DE NEMOURS & CO INC Address:1007 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-7515 Emergency Phone Num:800-441-3637 CAGE:0ERJ7 === Contractor Identification === Company Name:E I DUPONT DE NEMOURS & CO, INC. Address:1007 MARKET STREET City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515 CAGE:0ERJ7 Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:ING 17: THRU SKIN IN HARMFUL AMTS. ETHYL ACETATE: PRLNG/RPTD HIGH EXPOS OF LAB ANIMALS RSLTD IN SECONDARY (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: ANEMIA W/INCREASE IN WHITE BLOOD CELLS; FATTY DEGENERATION, CLOUDY SWELLING & EXCESS BLOOD IN VARIOUS ORGANS. RTECS #:9999999ZZ Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 3% OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 1% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER (PMGE ACETATE). VP: 3.8 @ 20C. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 14% Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 8% OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 28% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACRYLIC POLYMER. Ingred Name:SPILL PROC: DECONTAMINATE SOLN OVER SPILL & ALLOW TO SIT 10 MIN MINIMUM. TYPICAL DECONTAMINATION SOLNS ARE: (ING 10) RTECS #:9999999ZZ Ingred Name:ING 09: 20% SURFACTANT (TERGITOL TMN 10) AND 80% WATER; OR 0-10% AMMONIA, 2-5% DETERGENT, BALANCE WATER. RTECS #:9999999ZZ Ingred Name:SUPP DATA: IN LAB ANIMALS HAVE SHOWN REPRO, EMBRYOTOXIC & DEVELOPMENTAL EFTS. BUTYL ACETATE: RECURRENT OVEREXP (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: MAY RSLT IN LIVER/KIDNEY INJURY. TESTS FOR EMBRYOTOXIC ACTIVITY IN ANIMALS HAS BEEN INCONCLUSIVE. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: TOLUENE: RECURRENT OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRODUCED IRREG (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: HEART BEATS IN ANIMALS & OCCASIONAL PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH AIRBORNE LEVELS (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: HAVE EXHIBITED HIGH FREQ HEARING DEFICITS. THE SIGNIFICANCE TO MAN IS UNKNOWN. PMGE ACETATE: MAY CAUSE (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: MODERATE EYE BURNING. RECURRENT OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. XYLENE: HIGH CONC HAVE CAUSED (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: EMBRYOTOXIC EFTS IN LAB ANIMALS. RECURRENT OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. CAN BE ABSORBED (ING 18) RTECS #:9999999ZZ Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:GENL EFTS: INGEST: GI DISTRESS. INHAL: MAY CAUSE NOSE & THROAT IRRIT. RPTS/PRLNG OVEREXP TO SOLV MAY LEAD TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORD ARE SIGNS THAT SO LV LEVELS ARE TOO HIGH. EXPOS TO ISOCYANATES MAY CAUSE ASTHMA-LIKE RXNS W/SHORTNESS OF BREATH, (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:HLTH HAZ: WHEEZING, COUGH OR LUNG SENSIT. EFT MAY BE DELAYED FOR SEVERAL HRS AFTER EXPOS. INDIVIDUALS WITH LUNG/BRTHG PROBLEMS OR PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOS TO VAPS/SPRAY MIST OF PROD. EYE: MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CNTCT MAY CAUSE IRRIT W/DISCOMFORT & DERMATITIS. (SEE SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: IN THE UNLIKELY EVENT OF INGESTION, CALL MD IMMEDIATELY AND HAVE NAMES OF INGREDIENTS AVAILABLE. INHAL: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR. IF BREATHING DIFF ICULTY PERSISTS, OR OCCURS LATER, CONSULT MD. EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL MD. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION OCCURS, CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:20.0F,-6.7C Lower Limits:1% Upper Limits:13.1% Extinguishing Media:WATER SPRAY, FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS FLAMM VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW THE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT BREATHE VAPORS. DO NOT GET IN EYES/ON SKIN. WEAR A POS PRESS SUPPLIED AIR VAP/PARTICULATE RESP (NIOSH/MSHA TC-19C), CHEM WORK GOGGLES, GLOVES & PROT CLTHG. REMOVE SOURCES OF IGNITION. ABSORB W/ INERT MATL. VENT AREA. POUR LIQ (SEE INGRED 09) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PREC. KEEP AWAY FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F. Other Precautions:DO NOT BREATHE VAPORS OR MISTS. INDIVIDUALS WITH A HISTORY OF LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO ISOCYANATE SHOULD NOT USE OR BE EXPOSED TO THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR POS PRES SUPPLIED AIR RESP (NIOSH/MSHA TC-19C) WHILE MIXING ACTIVATOR W/ANY PAINT/CLEAR ENAMEL, DURING APPLICATN & UNTIL ALL VAPS/SPRAY MISTS EXHSTD. DO NOT PERMIT ANYONE W/O PROT IN PAINT AREA. FOLLOW RESP MFR'S DIRECTIONS FOR USE. Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS. Protective Gloves:NEOPRENE GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR SMOKING. Supplemental Safety and Health % VOLAT: 58.6-72.2 (VOL), 51.69-67.14 (WT). EFTS OF OVEREXP: SPECIAL EFTS: ACRYLIC POLYMER: RPTD/PRLNG LIQ CNTCT MAY CAUSE SKIN IRRIT W/DISCOMFORT & DERM. METHYL ISOBUTYL KETONE: RECURRENT OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. ETHYLBENZENE: RECURRENT OVEREXP MAY RSLT IN LIVER/KIDNEY INJURY. STUDIES (SEE INGRED 11) ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:169F,76C Vapor Pres:SEE INGRED Vapor Density:> AIR Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:MISCIBLE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO*2, SMOKE, OXIDES OF HEAVY METALS REPORTED IN THE INGREDIENTS SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.